The bonding environment of sorbed species at rock-water interfaces provides information on their mobility in natural systems. To investigate Pu sorption at a natural surface on a microscopic scale, we studied the bonding environment of sorbed Pu on zeolitic tuff with micro-XAS techniques. Using a focused 4 by 7 μm2 beam, XAS spectra were taken at Mn-smectite regions where high levels of sorbed Pu were found. The Pu did not sorb to Fe-rich regions. XANES spectra show the presence of Pu(VI), based on edge energy. Preliminary analyses of the micro-EXAFS spectra indicate the absence of a first shell splitting of axial and equatorial Pu-O bonds - an environment unlike what is observed for most hexavalent actinides.
