Chloroperoxidase-Catalyzed Epoxidation of Cis-β-Methylstyrene: NH-S Hydrogen Bonds and Proximal Helix Dipole Change the Catalytic Mechanism and Significantly Lower the Reaction Barrier Article

Morozov, Alexander N, Pardillo, Armando D, Chatfield, David C. (2015). Chloroperoxidase-Catalyzed Epoxidation of Cis-β-Methylstyrene: NH-S Hydrogen Bonds and Proximal Helix Dipole Change the Catalytic Mechanism and Significantly Lower the Reaction Barrier . JOURNAL OF PHYSICAL CHEMISTRY B, 119(45), 14350-14363. 10.1021/acs.jpcb.5b06731

cited authors

  • Morozov, Alexander N; Pardillo, Armando D; Chatfield, David C

sustainable development goals

authors

publication date

  • November 12, 2015

published in

keywords

  • ACTIVE-SITE
  • ALPHA-HELIX
  • COMPOUND-I
  • CRYSTAL-STRUCTURE
  • CYTOCHROME P450CAM
  • Chemistry
  • Chemistry, Physical
  • ELECTRON-PARAMAGNETIC-RESONANCE
  • HEME IRON
  • HIGHLY ENANTIOSELECTIVE EPOXIDATION
  • MOLECULAR-ORBITAL METHODS
  • Physical Sciences
  • Science & Technology
  • THIOLATE LIGAND

Digital Object Identifier (DOI)

publisher

  • AMER CHEMICAL SOC

start page

  • 14350

end page

  • 14363

volume

  • 119

issue

  • 45