The First Mixed Calcium Zinc Borate with a Flexible [B8 O17 ] Fundamental Building Block and Short UV Cutoff Edge. Article

Zhang, Wenbin, Guo, Siru, Han, Shujuan et al. (2021). The First Mixed Calcium Zinc Borate with a Flexible [B8 O17 ] Fundamental Building Block and Short UV Cutoff Edge. . CHEMISTRY-A EUROPEAN JOURNAL, 27(47), 12047-12051. 10.1002/chem.202101647

cited authors

  • Zhang, Wenbin; Guo, Siru; Han, Shujuan; Yang, Zhihua; Pan, Shilie

authors

abstract

  • The first mixed calcium zinc borate with a new fundamental building block (FBB) [B8 O17 ], Ca1.13 Zn0.87 B8 O14 has been successfully synthesized. It exhibits two independent interpenetrating three-dimensional B-O anion networks constructed by [B8 O17 ] groups, enriching the structural diversity of B-O configurations. In particular, the UV-Vis-NIR diffuse-reflectance spectrum shows that it has a short UV cutoff edge (<195 nm).

publication date

  • August 1, 2021

published in

Digital Object Identifier (DOI)

Medium

  • Print-Electronic

start page

  • 12047

end page

  • 12051

volume

  • 27

issue

  • 47