Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer Article

Bukhryakov, KV, Mugemana, C, Vu, KB et al. (2015). Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer . ORGANIC LETTERS, 17(19), 4826-4829. 10.1021/acs.orglett.5b02388

cited authors

  • Bukhryakov, KV; Mugemana, C; Vu, KB; Rodionov, VO

authors

abstract

  • An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst.

publication date

  • October 2, 2015

published in

Digital Object Identifier (DOI)

start page

  • 4826

end page

  • 4829

volume

  • 17

issue

  • 19